Oxidation kinetics for conversion of U3O8 to ε-UO3 with NO2
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منابع مشابه
Mechanism of the NO2 conversion to NO2- in an alkaline solution.
The reaction of NO2 and NaOH aqueous solution at room temperature was studied for elucidating the behavior of gaseous NO2 in an alkaline solution. Experimental runs related to NO2 absorption have been carried out in various pH solutions. The nitrite and nitrate ions formed in these absorption solutions were quantitatively analyzed. In the case of pH 5-12, both of the nitrite and nitrate ions we...
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Two types of ammonium uranyl nitrate (NH4)2UO2(NO3)4·2H2O and NH4UO2(NO3)3, were thermally decomposed and reduced in a TG-DTA unit in nitrogen, air, and hydrogen atmospheres. Various intermediate phases produced by the thermal decomposition and reduction process were investigated by an X-ray diffraction analysis and a TG/DTA analysis. Both (NH4)2UO2(NO3)4·2H2O and NH4UO2(NO3)3 decomposed to amo...
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The effects of different concentrations of CdCl2 and AlCl3 on NH4+ and NO2? oxidation in an aqueous system were investigated. AlCl3 had no effect on NH4+ removal and its oxidation to NO2?, whereas NO2? disappearance was greatly enhanced by AlCl3. In contrast, CdCl2 delayed removal of NH4+ and its subsequent oxidation to NO2? and also decreased the rate of NO2? disappearance. When compared to th...
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Pure borax and various boron compounds are produced from the solutions in which tincal is dissolved with various reagents. Economically important boron compounds such as boric acid, borax, boric oxide, and refined hydrated sodium borates and perborates are produced from boron-containing ores. The production of boric acid by using nitric acid from tincal is more advantageous because it evalu...
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ژورنال
عنوان ژورنال: Journal of Nuclear Materials
سال: 2017
ISSN: 0022-3115
DOI: 10.1016/j.jnucmat.2017.03.048